Nature of the band gap of In2O3 revealed by first-principles calculations and x-ray spectroscopy.
نویسندگان
چکیده
Bulk and surface sensitive x-ray spectroscopic techniques are applied in tandem to show that the valence band edge for In2O3 is found significantly closer to the bottom of the conduction band than expected on the basis of the widely quoted bulk band gap of 3.75 eV. First-principles theory shows that the upper valence bands of In2O3 exhibit a small dispersion and the conduction band minimum is positioned at Gamma. However, direct optical transitions give a minimal dipole intensity until 0.8 eV below the valence band maximum. The results set an upper limit on the fundamental band gap of 2.9 eV.
منابع مشابه
Synthesis of Sn 0.986 Ni 0.014 O Nanoparticles and Study of Their Optical Band Gap
Sn 0.986 Ni 0.014 O nanoparticles have been synthesized by a simple co-precipitation method. Nanoparticles crystallize in lower temperature (350°C) and shorter time (2h) respect to other methods. The sample characterized by various standard techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Atomic absorption spectroscopy (AAS) and UV–Vis spectroscopy. T...
متن کاملStructural Investigation, Physical and Optical Properties of Mixed Alkali Bismuth Borate Glasses
Lead free, eco-friendly bismuth borate glasses doped with alkali oxides of composition xLi2O+(30-x)Na2O+55B2O3+15Bi2O3 (x = 5,10,15,20,25) were prepared by melt quenching technique. Amorphous nature of glasses was confirmed by X-ray diffraction. Density measurements were carried out at room temperature by standard principle of Archimedes with Xylene as an immersion liquid. The non-linear ...
متن کاملFacile Synthesis and Spectroscopic Studies of SiO2-Core/ZnS-Shell Nanostructure
SiO2/ZnS core/shell nanostructures have been synthesized at room temperature by a simple wet chemical method. The prepared materials are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), infrared spectroscopy (IR), UV–vis spectroscopic and transmission electron microscopy (TEM) studies. X-ray diffraction pattern exhibits peaks correspond to the cubic phase of ZnS. Th...
متن کاملBand-Gap Tuning Of Electron Beam Evaporated Cds Thin Films
The effect of evaporation rate on structural, morphological and optical properties of electron beam evaporated CdS thin films have been investigated. CdS thin film deposited by electron beam evaporation method in 12nm/min and 60nm/min evaporation rates on glass substrates. X-ray diffraction, scanning electron microscopy, UV-Vis-NIR spectroscopy and Atomic Force Microscopy were used to character...
متن کاملA QUICK ROUTE FOR THE SYNTHESIS OF PMN-PZT POWDERS
In the following research, Lead magnesium niobate relaxor ferroelectric (PMN-PZT) ceramic powders were synthesized using the combustion method grand urea as the fuel for the first time. The starting materials used were lead nitrate, magnesium acetate, niobium oxide, zirconium nitrate, titanium oxide. The raw materials were first mixed using the general formula of (1-x)Pb(M...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 100 16 شماره
صفحات -
تاریخ انتشار 2008